CORK
TAINT can most accurately be
described as "moldy" or "musty" or "earthy" or sometimes "medicinal"
smell that masks or dominates the fruit aroma of wine and reduces the
overall wine quality. The source may be one or more particular chemical
compounds formed by a reaction between molds and chemicals. Infected wines are said to be "corked"
or "corky" and the contaminant often referred to as "cork taint", although
there are many other possible sources besides corks for its presence in
wine. Molds may be originally present in raw
cork bark or in wood used for barrels or barrel racks, tanks, scaffolding,
walls, stairs, pallets, cardboard boxes, or other many other types of
winery equipment or facilities. TCA can also can infect cork or wood that
is in storage. Ironically, chemicals used for keeping
the production environment sterile and safe from contmination become
degraded by fungi or molds indigenous to wood products. The main culprit
is thought to be chlorine bleach used in cork processing and also as
a routine disinfectant in wineries. Common treatments such as insecticides,
pesticides, herbicides, or flame-retardants, although no longer used
on vines or even legal in some cases are also identified sources. Another
possibility is atmospheric pollution by off-gassing from plastic equipment,
or simply from old wooden buildings that have absorbed any of these
chemical pollutants over time. Regardless of the source or chemical
identity, Cork Taint can impart a very unpleasant smell that, depending
upon its severity, tends to dominate all other aroma characteristics
of any wine it contaminates. The least offensive and most subtle sign
of TCA is wine that has very little aroma at all. The Australian
Wine Research Institute conducted experiments in early 2003, that
demonstrated even a very low level of contamination, as little as
one or two nanograms per litre, suppresses positive fruit aroma character
in wine by as much as 50%. As with all aromas, individuals vary in
their threshold ability to detect the presence and strength of Cork Taint,
as well as their tolerance for it; experience can increase sensitivity.
The human threshold for detection is generally considered to be above
5 nanograms per litre. Damage to the wine industry annually
from Cork Taint is estimated to be $10-billion worldwide. A reliable
process has been developed to detect and remove TCA from wine before
it is bottled.
While TCA can be detected in corks, however,
there is of yet no proven method to remove it from this source. This presents
both a complex challenge to wine science and mutual frustrations to the
wine and cork industries. Experiments are ongoing to prevent or purge
TCA from corks, using alternative chemical treatments, steam, gas emersion,
microwaving, etc. For a more detailed
explanation of TCA-related wine spoilage, see
Cork
Taint: TCA and Related
Compounds, a web
project of Professor Andrew Waterhouse's Students of Natural
Products of Wine at the University of California at Davis.
In terms of providing a thorough explanation of wine
chemistry that can be easily understood by a layman, this is
one of the very best articles on the Internet.
TCA
is the common abbreviation for the chemical compound 2,4,6-trichloroanisole,
the first source identified and thought to be the primary cause of cork
taint. Other chloroanisole contaminants of wine may include 2,3,4,6-tetrachloroanisole
(TeCA) and pentachloroanisole (PCA). Scientists in Bordeaux, France,
using gas chromatography and mass spectrometry, have recently isolated
another compound, 2,4,6-tribromoanisole
(TBA), that similarly ruins wine aromas.
Page created September 25,
2002; updated
September 5, 2008
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